常见溶剂的化学位移

mult.

氘 代 溶 剂

CDCl3

(CD3)2CO

(CD3)2SO

C6D6

CD3CN

CD3OD

D2O

C5D5N

残余溶剂峰

7.26

2.05

2.50

7.16

1.94

3.31

4.79

7.20

7.57

8.72

水峰

brs

1.56

2.84

3.33

0.40

2.13

4.87

4.79

4.96

CHCl3

s

7.26

8.02

8.32

6.15

7.58

7.90

　(CH3)2CO

s

2.17

2.09

2.09

1.55

2.08

2.15

2.22

(CH3)2SO

s

2.62

2.52

2.54

1.68

2.50

2.65

2.71

C6H6

s

7.36

7.36

7.37

7.15

7.37

7.33

CH3CN

s

2.10

2.05

2.07

1.55

1.96

2.03

2.06

CH3OH

CH3,s

OH,s

3.49

1.09

3.31

3.12

3.16

4.01

3.07

3.28

2.16

3.34

3.34

C5H5N

CH(2),m

CH(3),m

CH(4),m

8.62

7.29

7.68

8.58

7.35

7.76

8.58

7.39

7.79

8.53

6.66

6.98

8.57

7.33

7.73

8.53

7.44

7.85

8.52

7.45

7.87

8.72

7.20

7.57

CH3COOC2H5

CH3,s

CH2,q

CH3,t

2.05

4.12

1.26

1.97

4.05

1.20

1.99

4.03

1.17

1.65

3.89

0.92

1.97

4.06

1.20

2.01

4.09

1.24

2.07

4.14

1.24

CH2Cl2

s

5.30

5.63

5.76

4.27

5.44

5.49

n-hexane

CH3,t

CH2,m

0.88

1.26

0.88

1.28

0.86

1.25

0.89

1.24

0.89

1.28

0.90

1.29

C2H5OH

CH3,t

CH2,q

1.25

3.72

1.12

3.57

1.06

3.44

0.96

3.34

1.12

3.54

1.19

3.60

1.17

3.65

氘 代 溶 剂

CDCl3

(CD3)2CO

(CD3)2SO

C6D6

CD3CN

CD3OD

D2O

C5D5N

溶剂峰

77.16

206.26

29.84

39.52

128.06

1.32

118.26

49.00

-

123.44

135.43

149.84

CHCl3

77.36

79.19

79.16

77.79

79.17

79.44

　(CH3)2CO

207.07

30.92

205.87

30.60

206.31

30.56

204.43

30.14

207.43

30.91

209.67

30.67

215.94

30.89

(CH3)2SO

40.76

41.23

40.45

40.03

41.31

40.45

39.39

C6H6

128.37

129.15

128.30

128.62

129.32

129.34

CH3CN

116.43

1.89

117.60

1.12

117.91

1.03

116.02

0.20

118.26

1.79

118.06

0.85

119.68

1.47

CH3OH

50.41

49.77

48.59

49.97

49.90

49.86

49.50

C5H5N

149.90

123.75

135.96

150.67

124.57

136.56

149.58

123.84

136.05

150.27

123.58

135.28

150.76

127.76

136.89

150.07

125.53

138.35

149.18

125.12

138.27

CH3COOC2H5

21.04

171.36

60.49

14.19

20.83

170.96

60.56

14.50

20.68

170.31

59.74

14.40

20.56

170.44

60.21

14.19

21.16

171.68

60.98

14.54

20.88

172.89

61.50

14.49

21.15

175.26

62.32

13.92

CH2Cl2

53.52

54.95

54.84

53.46

55.32

54.78

n-hexane

14.14

22.70

31.64

14.34

23.28

32.30

13.88

22.05

30.95

14.32

23.04

31.96

14.43

23.40

32.36

14.45

23.68

32.73

C2H5OH

18.41

58.28

18.89

57.72

18.51

56.07

18.72

57.86

18.80

57.96

18.40

58.26

17.47

58.05